++MPP-W43C
Northstar Polymers, LLC
3444 Dight Avenue So.
Minneapolis, MN 55406
Tel: 612.721.2911
Fax: 612.721.1009
E-Mail: info@northstarpolymers.com
Northstar Polymers, LLC is a member of Polyurethane Manufacturers Association.
Copy right reserved by Northstar Polymers, LLC 2000 - 2007.
MPP-W43C
OOO Scale Gel
MPP-W43C is one of our polyurethane gel formulations specifically designed for padding and cushioning applications that require Shore Durometer OOO scale hardness materials. With this material, a user can obtain good rebound characteristics and gradual compression deflection rates at the Shore OOO hardness range. The material does not contain any plasticizer, which is known to leach out to have adverse effect to the plastic film encapsulation materials used in conjunction with gel materials.
This newly developed formula uses the same part-B (PNA-157) as our standard Shore OO polyurethane gel. This allows you to make variety products with fewer raw material inventories. The applications for this material include cushioning and padding parts for medical/semi-medical application, fiber optic cable encapsulation, novelty products, and many more.
This polyurethane gel material is formulated in such a way that the user can control/choose the hardness/deflection properties of the product. Following is reference for the hardness to the corresponding mixing ratio.
Hardness vs. Mixing Ratio Correlation
|
NCO Stoichiometric Ratio |
OH Stoichiometric Ratio |
Part-A Weight Ratio |
Part-B Weight Ratio |
Part-A Volume Ratio |
Part-B Volume Ratio |
Hardness OOO (Reference Only) |
|
1.000 |
2.200 |
1.000 |
4.009 |
1.000 |
4.173 |
65 |
|
1.000 |
2.500 |
1.000 |
4.556 |
1.000 |
4.742 |
55 |
|
1.000 |
2.800 |
1.000 |
5.103 |
1.000 |
5.311 |
40 |
|
1.000 |
2.900 |
1.000 |
5.285 |
1.000 |
5.500 |
35 |
|
1.000 |
3.000 |
1.000 |
5.467 |
1.000 |
5.690 |
30 |
|
1.000 |
3.100 |
1.000 |
5.650 |
1.000 |
5.880 |
25 |
*The product hardness is more directly related with the stoichiometry ratios between the mole numbers and functionality of NCO and OH functional terminals. However, in practice, you may use weight ratio or volume ratio for the parameter value to determine the targeted hardness for the hardness specification ranges for the most common applications. Please contact Northstar Polymers for more precise method of hardness control.
The above is the result of our lab tests, and it is reference only. The hardness are typical values within + or - 5 Durometer units. The data is guidance only. The user must test the mixing ratio and yielding hardness for each application.
Harder products have faster rebound time after compression force is released. Softer materials have more viscoelastic properties, and hardness reading changes while you press the Durometer probe on into the material.
Components:
Part-A: MPC-070
Part-B: PNA-157
Processing Conditions
Processing Temperature:
Part-A: Room Temperature
Part-B: Room Temperature
Mold: Room Temperature
Curing Pattern
Pot life: 5 minutes at ambient temperature
Demolding: 2 – 5 hours at ambient temperature
Complete Cure: 1 to 2 days at ambient temperature
Note: This curing pattern data is yield from 1:5.2 mixing ratio at room temperature. The curing rate may vary depending on the mixing ratio chosen for the process. The curing pattern can be modified by addition of a catalyst. Please consult Northstar Polymers for the modification.
Recommendations
Mixing ratio setting for your dispensing equipment is critical to the hardness determination. We recommend the mixing ratio is calibrated by actual weight ratio of the material dispensed from the machine. For tighter control of the product hardness, recalculation of the volume ratio based on the actual values of the Certificates of Analysis may be required for each lot of material. Please consult Northstar Polymers for the detailed information on recalculation and calibration.
Part-A material is highly viscous at a room temperature. If casting machine is used for high volume production, part-A can be heated between 140 and 160 °F to lower the viscosity; this helps mixing the components well. Higher processing temperature will increase the cure rate. Also, catalyst can be used to increase the production rate.
This material is often encapsulated with coated cloth material, polyurethane film, or other resilient materials. The surface of gel product is very sticky, and the gel can be cut or torn easily in certain applications. The encapsulation is essential for protection of the gel in some applications. For temporary handling, you may use talc powder to prevent it from sticking to the handlers or equipment.
Use of elevated temperature may cause shrinkage of this material. Shrinkage will be a critical issue if you are pouring this material directly on a flexible film. Shrinkage could cause significant wrinkling of the film. If excessive wrinkle occurs, the processing rate may need to be slowed.
Component Data:
Part-A
|
Product Code: |
MPC-070 |
|
Description: |
Isocyanate terminated prepolymer extended with polyether polyol |
|
%NCO: |
5.0 % +, - 0.5% |
|
Amine Equivalent |
830 - 850 |
|
Specific Gravity: |
1.066 |
|
Physical State at 25 °C ( 77 °F): |
Liquid (dark yellow color)
|
|
Viscosity at 25 °C (77 °F): |
50,000 – 100,00 cps |
|
Storage: |
Store in a dry indoor storage at room temperature. The material is highly sensitive to moisture. After using the content, immediately inject dry nitrogen gas or argon gas into the container to purge and blanket the top space then store in the original airtight container. Heat will accelerate the subsequent reaction within the material and shorten the shelf life of the material. Do not store at an elevated temperature. Recommended storage temperature is 70 to 90 °F. |
Note: Part-A component "MPC-070" contains dark, viscous sediment. This is a bi-product, which we cannot avoid making when we produce this material. If this material enters into the final product, it can cause inconsistent hardness and bad appearance. We recommend avoiding use of the small amount of this sediment at the bottom of the container.
Part-B
|
Product Code: |
PNA-157 |
|
Description: |
Curing agent based on a blend of polyether polyols and additives |
|
Equivalent Weight: |
1530 - 1580 |
|
Specific Gravity: |
1.024 |
|
Physical State at 25 °C ( 77 °F): |
Liquid (clear with some off-white haze)
|
|
Viscosity at 25 °C (77 °F) |
700 – 1100 cps |
|
Storage: |
Store in a dry indoor storage at room temperature. The material is hygroscopic. For long term storage, inject dry nitrogen gas or -40° due-point dry air into the container to blanket the material. |
Handling Information:
Safety:
The component materials are industrial-grade chemicals. Please keep them in a secure place and prevent access from any unauthorized individual. The personnel who handles these materials needs to read the Material Safety Data Sheet (MSDS) for detail information on safety and handling of the material. The MSDS for each component is sent with the shipment of the material.
When you are conducting a test, or producing your parts using this material, please be sure to operate in a wide-open area with good air movement, or in a well-ventilated area. Wear rubber gloves, long sleeves, and protective eyeglasses to prevent skin/eye contact of the material. When your operation involves heating or spraying of the material, we recommend, in addition to the above, installation of a proper dynamic ventilation system and/or using a half-face respirator to prevent inhalation of the fume.
Direct contact of polyurethane raw materials to skin/eye, as well as ingestion may lead to health problems. No eating or smoking should be permitted at the working area. The operator should wash hands well with soap and water after handling the materials. Please refer to the Material Safety Data Sheet for each component for the detailed health information.
Storage:
Part-A component (prepolymer) contains isocyanate component, which is very much sensitive to moisture. If it is left in air, part-A component will react with atmospheric moisture and will be ruined. This reaction is non-reversible. Soon after opening a can and dispensing the content, nitrogen gas, argon gas, or negative-40-degree-due-point dry air needs to be injected to the container to blanket the material. Silica gel or calcium chloride desiccant filter should be installed to 55 gallon drum-vent for your drum dispensing system. The storage temperature should be at a room temperature between 65 and 90 ºF.
Part-B component is hygroscopic. If the material is exposed to ambient air, it may absorb moisture. Moisture contaminated part-B material may become source of degradation or excessive bubbles in the product. Avoid exposure of the material to air. Purging the empty space in the container with nitrogen gas or negative-40-degree-due-point dry air is also recommended to prevent moisture contamination of part-B. The storage temperature should be at a room temperature between 65 and 90 ºF. Store the containers in a dry indoor space.
For any questions, please contact Northstar Polymers.
Tel: 612-721-2911.
Fax: 612-721-1009
Web Site: http://www.northstarpolymers.com
E-Mail: info@northstarpolymers.com
Notice: All of the statements, recommendations, suggestions, and data concerning the subject material are based on our laboratory results, and although we believe the same to be reliable, we expressly do not represent, warrant, or guarantee the accuracy, completeness, or reliability of same, or the material or the results to be obtained from the use thereof, neither do we warrant that any such use, either alone or in combination with other materials, shall be free of the rightful claim of any third party by way of INFRINGEMENT or the like, and NORTHSTAR POLYMERS DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, OF MERCHANTABILITY and FITNESS FOR A PARTICULAR PURPOSE.
Revised 1/07/2009
Processing Instructions for Test Mix
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For any questions, please feel free to contact us:
Northstar Polymers, LLC
3444 Dight Avenue South
Minneapolis, MN 55406
Tel: 612.721.2911
Fax: 612.721.1009
E-Mail: info@northstarpolymers.com